ASTM E727/E727M-2008 应用统计质量保证和控制图表技术评估分析测量系统性能的标准实施规程

作者:标准资料网 时间:2024-05-19 05:29:44   浏览:9077   来源:标准资料网
下载地址: 点击此处下载
【英文标准名称】:StandardPracticeforApplyingStatisticalQualityAssuranceandControlChartingTechniquestoEvaluateAnalyticalMeasurementSystemPerformance
【原文标准名称】:应用统计质量保证和控制图表技术评估分析测量系统性能的标准实施规程
【标准号】:ASTME727/E727M-2008
【标准状态】:现行
【国别】:美国
【发布日期】:2008
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:E35.22
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:
【英文主题词】:bulk;density;measuring;carriers;loose-fill
【摘要】:Thesetestmethodisdesignedprincipallywithclay,corncob,nutshell,paper-basedorsandgranularcarriers,andgranularpesticideproducts,butneednotbelimitedtothesematerials.Theremaybemoreappropriatetestmethodsforothertypesofgranularcarriersorpesticideproducts.Thedifferencesinthefollowingtestmethodsareslight,buttheyofferachoiceofarecognizedtestprocedure.1.1Thispracticecoversinformationforthedesignandoperationofaprogramtomonitorandcontrolongoingstabilityandprecisionandbiasperformanceofselectedanalyticalmeasurementsystemsusingacollectionofgenerallyacceptedstatisticalqualitycontrol(SQC)proceduresandtools.Note1Acompletelistofcriteriaforselectingmeasurementsystemstowhichthispracticeshouldbeappliedandfordeterminingthefrequencyatwhichitshouldbeappliedisbeyondthescopeofthispractice.However,somefactorstobeconsideredinclude(1)frequencyofuseoftheanalyticalmeasurementsystem,(2)criticalityoftheparameterbeingmeasured,(3)systemstabilityandprecisionperformancebasedonhistoricaldata,(4)businesseconomics,and(5)regulatory,contractual,ortestmethodrequirements.1.2Thispracticeisapplicabletostableanalyticalmeasurementsystemsthatproduceresultsonacontinuousnumericalscale.1.3Thispracticeisapplicabletolaboratorytestmethods.1.4Thispracticeisapplicabletovalidatedprocessstreamanalyzers.1.5ThispracticeisapplicabletomonitoringthedifferencesbetweentwoanalyticalmeasurementsystemsthatpurporttomeasurethesamepropertyprovidedthatbothsystemshavebeenassessedinaccordancewiththestatisticalmethodologyinPracticeD6708andtheappropriatebiasapplied.Note2Forvalidationofunivariateprocessstreamanalyzers,seealsoPracticeD3764.Note3Oneorbothoftheanalyticalsystemsincanbelaboratorytestmethodsorvalidatedprocessstreamanalyzers.1.6Thispracticeassumesthatthenormal(Gaussian)modelisadequateforthedescriptionandpredictionofmeasurementsystembehaviorwhenitisinastateofstatisticalcontrol.Note4Fornon-Gaussianprocesses,transformationsoftestresultsmaypermitproperapplicationofthesetools.Consultastatisticianforfurtherguidanceandinformation.
【中国标准分类号】:B17
【国际标准分类号】:65_100_01
【页数】:2P.;A4
【正文语种】:英语


下载地址: 点击此处下载
【英文标准名称】:StandardTestMethodforDeterminationofParentandAlkylPolycyclicAromaticsinSedimentPoreWaterUsingSolid-PhaseMicroextractionandGasChromatography/MassSpectrometryinSelectedIonMonitoringMode
【原文标准名称】:在选定的离子监控模式下用固相微萃取法和气相色谱/质谱法测定沉积物孔隙水中母体芳烃和烷基多环芳烃的标准试验方法
【标准号】:ASTMD7363-2007
【标准状态】:现行
【国别】:
【发布日期】:2007
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D19.06
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:烷基;芳香的;芳香族化合物;化学特性;测定;气相色谱法;离子;质谱学;监控;孔隙;断面图;沉积物;土壤普查;固相微萃取法;测试;水
【英文主题词】:
【摘要】:ThismethoddirectlydeterminestheconcentrationsofdissolvedPAHconcentrationsinenvironmentalsedimentporewatersamples.ThemethodisimportantfromanenvironmentalregulatoryperspectivebecauseitcanachievetheanalyticalsensitivitiestomeetthegoalsoftheUSEPAnarcosismodelforprotectingbenthicorganismsinPAHcontaminatedsediments.Regulatorymethodsusingsolventextractionhavenotachievedthewidecalibrationrangesfromnanogramstomilligramsperlitreandtherequiredlevelsofdetectioninthenanogram-per-litrerange.Inaddition,conventionalsolventextractionmethodsrequirelargealiquotvolumes(litreorlarger),useoflargevolumesoforganicsolvents,andfiltrationtogeneratetheporewater.ThisapproachentailsthestorageandprocessingoflargevolumesofsedimentsamplesandlossoflowmolecularweightPAHsinthefiltrationandsolventevaporationsteps.ThismethodcanbeusedtodeterminenanogramtomilligramperlitrePAHconcentrationsinporewater.SmallvolumesofporewaterarerequiredforSPMEextraction,only1.5mLperdeterminationandvirtuallynosolventextractionwasteisgenerated.1.1TheU.S.EnvironmentalProtectionAgency(USEPA)narcosismodelforbenthicorganismsinsedimentscontaminatedwithpolycyclicaromatichydrocarbons(PAHs)isbasedontheconcentrationsofdissolvedPAHsintheinterstitialwateror"porewater"insediment.ThistestmethodcoverstheseparationofporewaterfromPAH-impactedsedimentsamples,theremovalofcolloids,andthesubsequentmeasurementofdissolvedconcentrationsoftherequired10parentPAHsand14groupsofalkylateddaughterPAHsintheporewatersamples.The"24PAHs"aredeterminedusingsolid-phasemicroextraction(SPME)followedbyGasChromatography/MassSpectrometry(GC/MS)analysisinselectedionmonitoring(SIM)mode.Isotopicallylabeledanalogsofthetargetcompoundsareintroducedpriortotheextraction,andareusedasquantificationreferences.1.2LowermolecularweightPAHsaremorewatersolublethanhighermolecularweightPAHs.Therefore,USEPA-regulatedPAHconcentrationsinporewatersamplesvarywidelyduetodifferingsaturationwatersolubilitiesthatrangefrom0.2956g/Lforindeno[1,2,3-cd]pyreneto31000956g/Lfornaphthalene.ThismethodcanaccommodatethemeasurementofmilligramperlitreconcentrationsforlowmolecularweightPAHsandnanogramperlitreconcentrationsforhighmolecularweightPAHs.1.3TheUSEPAnarcosismodelpredictstoxicitytobenthicorganismsifthesumofthetoxicunits(TUc)calculatedforall"34PAHs"measuredinaporewatersampleisgreaterthanorequalto1.Forthisreason,theperformancelimitrequiredfortheindividualPAHmeasurementsweredefinedastheconcentrationofanindividualPAHthatwouldyield1/34ofatoxicunit(TU).However,thefocusofthismethodisthe10parentPAHsand14groupsofalkylatedPAHs()thatcontribute95%ofthetoxicunitsbasedontheanalysisof120backgroundandimpactedsedimentporewatersamples.Theprimaryreasonsforeliminatingtherestofthe5-6ringparentPAHsare:(1)thesePAHscontributeinsignificantlytotheporewaterTU,and(2)thesePAHsexhibitextremelylowsaturationsolubilitiesthatwillmakethedetectionofthesecompoundsdifficultinporewater.Thismethodcanachievetherequireddetectionlimits,whichrangefromapproximately0.01956g/L,forhighmolecularweightPAHs,toapproximately3956g/LforhighmolecularweightPAHs.1.4ThetestmethodmayalsobeappliedtothedeterminationofadditionalPAHcompounds(forexample,5-and6-ringPAHsasdescribedinHawthorneetal).However,itistheresponsibilityoftheuserofthisstandardtoestablishthevalidityofthetestmethodforthedeterminationofPAHsotherthanthosereferencedin1.1andTable1.Thisst......
【中国标准分类号】:G17
【国际标准分类号】:13_080_10
【页数】:23P.;A4
【正文语种】:


基本信息
标准名称:手柄
中标分类: 机械 >> 通用零部件 >> 操作件
替代情况:HB 2997-1981
发布日期:2000-09-21
实施日期:2001-01-01
首发日期:1900-01-01
作废日期:1900-01-01
出版日期:1900-01-01
适用范围

未出版

前言

没有内容

目录

没有内容

引用标准

没有内容

所属分类: 机械 通用零部件 操作件